Those types of coolant will only work if they are allowed to evaporate or change states. As a transfer medium, they are less than desirable. Water is the best transfer medium that is both readily available and cheep. The other coolants you mention will work very well as a spray to help cool the heat exchanger from the outside. The evaporative effect of those liquids is far better than water and, when used in that manner, have the potential to cool the output of the heat exchanger to below ambient temperature.
One thing you could do is use a surfactant in the water to break down the surface tension of the water to allow better contact with the metal surfaces inside the heat exchanger thereby improving thermal transfer. They call this water wetter.
Subsequently my device incorporates an IC spray feature and I plan on using a 50/50 mix of water to alcohol to take advantage of the evaporative effects. I can't wait to start testing this system as a whole because though one part may not have the biggest impact, all of them together will.